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Type: 
Journal
Description: 
A simple and effective approach to fabricate extensive 3D ZnO nanoarchitectures on alkaline etched (100) Si substrates is presented. Textured silicon micropattern drives ZnO 1D growth on all the {111} exposed faces, resulting in sea sponge-likeZnO nanoarchitectures. The obtained 3D nanostructured ZnO is the result of a perfectly ordered array of continuous and crystalline ZnO nanorods, grown on the silicon pyramid {111} faces. The substrate orientation and the relative roughness, intrinsically derived by the alkaline silicon texturization, drive the preferential growth of one-dimensional ZnO nanorods. The ZnO nanorods photoluminescence spectra show, at room temperature, a narrow ultraviolet (UV) emission peak at 3.28 eV and a broad unstructured green band emission at 2.57 eV. These luminescence emissions are attributed to the near band-edge exciton transitions and to the defect emission, respectively …
Publisher: 
Royal Society of Chemistry
Publication date: 
1 Jan 2009
Authors: 

Maria Elena Fragalà, Alessandro Di Mauro, Grazia Litrico, Filippo Grassia, Graziella Malandrino, Gaetano Foti

Biblio References: 
Volume: 11 Issue: 12 Pages: 2770-2775
Origin: 
CrystEngComm